An introduction to the quantitative use of phase diagrams in igneous petrology geochemistry and petrology of igneous assemblage in the south of qorveh area, west iran pdf. River basalts and the ontong java plateau as examples. Stolper e 1980 a phase diagram for midocean ridge basalts. Many factors influenced the mare basalt crystallization sequence. An introduction to the quantitative use of phase diagrams in igneous petrology. Phase diagrams indicate phases as function of t, co, and p. Phase diagrams are graphical representations that help us understand. Composition and depth of origin of primary midocean ridge.
Basalt flows emanating from the uinkaret field between the hurricane and toroweep faults spilled into the grand canyon as shown in figure 14. Highpressure phase equilibria of a highmagnesia basalt and the. Morbnormalized spider diagram for some representative analyses from the crb flood basalts data from hooper and hawkesworth 1993 j. We present the results of highpressure, hightemperature phase equilibrium experiments on the gusev basalts. An introduction to the quantitative use of phase diagrams. Isomolar and isostructural pseudoliquidus phase diagrams for. Morse pdf download free book basalts and phase diagrams. Highpressure phase equilibria of a highmagnesia basalt.
The volume includes 1083 binary systems, 1095 binary diagrams, 115 ternary systems, and 406 ternary. Basalts by contrast are volcanic rocks composed of a paste of microscopic crystals. Students are provided with the phase diagram and asked to answer questions about it. Max concentration for which only a single phase solution occurs. The tetrahedron is constructed using the normative components olivine, quartz, clinopyroxene, and nepheline. High pressure phase relations of primitive highalumina. Experimentally based water budgets for dehydrating slabs and. Homework 6 ternary phase diagrams isotope chemistry of the. The simplest type of diagram to generate is the version of the wo projection illus. Igneous rock classification using diagrams thoughtco. Introduction to materials science chapter 9, phase diagrams 6 phase diagramis a graphical representation of all the equilibrium phases as a function of temperature, pressure, and composition. Composition and depth of origin of primary midocean ridge basalts reply to d. Basalt is an easily datable rock and thus is a handy tool when available. The basalt tetrahedron is a useful tool for classifying basalts.
It is the rock formed at midocean ridges and, therefore, beneath a thin layer of sediment, is found nearly everywhere at the bottom of the ocean. Although phase diagrams and experimental studies can be used to predict the initial crystallizing phases, metastable chemical trends in minerals and delayed nucleation of some phases often. Petrology and geochemistry of basalts from tonnge area, tigyaing township, sagaing region, myanmar abstract fulltext html xml download as pdf size. Owing to the aphanitic texture of volcanic and hypabyssal rocks, their modes cannot be readily determined. Experimentally based water budgets for dehydrating slabs. Isobaric diagram illustrating the liquidus temperatures in the system diopsideanorthitealbite at atmospheric pressure 0. Phase behavior of lipid mixtures pubmed central pmc. In ternary phase diagrams, all crystalline phases are.
A continental within plate character is recognized for both the yts and yvs basalts. Asimow geological and planetary sciences, california institute of technology, pasadena, california 91125, usa. The global systematics of ocean ridge basalts and their origin allison gale. Petrology and geochemistry of basalts from tonnge area. Selecting for ocean ridge basalts with 9 wt % mgo leads to a disproportionately high number of hial basaltsa distinct and unusual magma seriesin the dataset. Acf diagrams one of the first uses of these types of diagrams was by eskola 1915 who employed a diagram known as the acf diagram in his study of metamorphic rocks. These basalts are represented by the rocks humphrey, adirondack, and mazatzal, and have been classified by squyres et al.
An introduction to the quantitative use of phase diagrams in igneous petrology s. The phase relations of quaternary systems are generally represented by projections onto ternary compositional planes. Although some information is lost in the projection, we can still treat these two phase diagrams in the same way that we treat normal phase diagrams. Basalts and phase diagrams an introduction to the quantitative use of phase diagrams in igneous petrology geochemistry and petrology of igneous assemblage in the south of qorveh area, west iran geodynamic evolution of the central and western mediterranean. Igneous rock classification of volcanic and hypabyssal.
Isobaric diagram illustrating the liquidus temperatures in the dianfo system at atmospheric pressure 0. Basalts, basalt series, and basalt classification basalt. Mantle melting and the generation of basaltic magma. The phase diagram of whole rock mantle compositions is an es. The tetrahedral plot requires that compositions of the minerals and melts be transformed into cartesian coordinates. Krieger publushers isobaric polythermal projection isobaric diagram illustrating the liquidus temperatures in the system diopsideanorthitealbite at atmospheric pressure 0. The highpressure phase equilibria determined in this study, supplemented with the results obtained on other tholeiitic basalt compositions, are used to construct pseudoliquidus phase diagrams for evaluating and predicting the nature of primary magmas and melting of the mantle at high pressures. Phase diagrams have been prepared from the experimental studies of. Other terms that have commonly been used to describe morb include ocean ridge basalts. Basalts and gabbros binary systems with solid solution binary systems with a eutectic binary systems with a a reaction point ternary systems magmatic system melt generation melt migration intermediate chambers crystallization eruption onto surface phase diagrams tpx space system. Phase diagrams phase a phase b nickel atom copper atom chapter 9 2 phase equilibria. Trace elements in igneous petrology university of washington.
Temperature increases perpendicular to the plane of the diagram and any plane through the ternary is similar to a binary diagram and called a. Three component phase diagrams ternary plots ternary diagrams have three endmembers located at the vertices of a triangular plot. This is illustrated, for example, in the plagioclasediopside ternary phase diagram common in petrology. An introduction to the quantitative use of phase diagrams in igneous petrology softcover reprint of the original 1st ed.
Petrography and petrogenesis of a midocean ridge lava suite. Comparative liquidus equilibria of hypersthenenormative. These substances constitute the components comprising the system and should not be confused with the various phases found within the system. They will be referred to in this paper as gusev basalts. Volume 3 provides a complete explanation of phase diagrams and their significance and covers solid solutions.
Ternary phase diagrams finish questions 1015 on the dianfo ternary diagram worksheet we partially completed in class on friday, may 26. Phase diagrams of hydrous midocean ridge mor basalts to 330 km depth and of hydrous peridotites to 250 km depth are compiled for conditions characteristic for subduction zones. A synthesis of our experimentally determined phase relations of chlorite, lawsonite, epidotezoisite, amphibole, paragonite, chloritoid, talc, and phengite in basalts. Introduction to materials science chapter 9, phase diagrams 10 a phase diagrams show what phases exist at equilibrium and what phase transformations we can expect when we change one of the parameters of the system. Numbers next to data points represent calculated water contents of liquid according to the solubility model of 8. Stolper e 1980 phase diagram for midocean ridge basalts. Highly undesaturated nephelinebearing alkali olivine. Liquidus resembles 3 hills with summits at an, di and fo with intervening valleys cotectics arrows indicate decreasing temperature crystallization relationships liquid a will begin to crystallize forsterite at 17000c. Other relevant phase boundaries, such as olsil, silplag, and plagsp are approximated by extrapolation. Liquidus resembles 3 hills with summits at an, di and fo with intervening valleys cotectics arrows. Petrology and geochemistry of basalts and related rocks table 2 comparative analyses of basalts from site 215 and those from other oceanic regions sio2 a12o3 fe2o3 feo mgo cao na2o k2o tio2 p2 5 ignition loss b ba co cr cu ga li mo ni sr u v y zr sitea 215 49.
With these expressions it is a straightforward process to test a basaltic composition for its liquidus phase or to construct a phase diagram. One popular scheme is based on the use of both chemical components and normative mineralogy. Readings advanced igneous petrology earth, atmospheric. Pdf a users guide to basalt discrimination diagrams. For one component systems, the equilibrium state of the system is defined by two independent parameters p and t, t and v, or p and v. For example, in the olivineopxqtz system, melting involves a reaction relation peritectic. Magmas of the yts were erupted during the synrift phase and correlate with the first stage of seafloor spreading of the red sea and the gulf of aden 30 15 ma, whereas the magmas of the yvs were emplaced during the post rift phase 10 0 ma. The use of these pseudoliquidus phase diagrams for evaluating the. Pearce and others published a users guide to basalt discrimination diagrams find, read and cite all the research you need on researchgate. Igneous rock igneous rock classification of volcanic and hypabyssal rocks. In fact, complexities involving the petrogenesis of hial lavas have led to their exclusion in this study, despite their primitive nature see supplementary data. A system, how ever, also can consist of a single component, such as an element or compound. An introduction to the quantitative use of phase diagrams in igneous petrology pdf, download basalts and phase diagrams. Geologists usually use the tas classification because its more consistent.
The origin and fate of basaltic magma is still unfolding. This explanation seems to be supported by projections in phase diagrams where the coib, except for some highly alkaline basalts, overlap with volatilefree peridotite melts fig. Real materials are almost always mixtures of different elements rather than pure substances. Give the names for the single phases in the snbi system 2. These basalts have been used to determine colorado river incision rates. Similar basalts erupt in rift zones on continents, such as in the connecticut valley. These are an analog for the crystallization of basaltic melts. Di an eutectic di ab eutectic ab an solid solution isobaric polythermal projection.
Phlog phlogopite, oliv olivine, mgnt magnetite, aug augite, apat apatite, liq liquid. An introduction to the quantitative use of phase diagrams in igneous petrology geochemistry and petrology of igneous assemblage in the south of qorveh area, west iran pdf reader. Homework 6 ternary phase diagrams isotope chemistry of. Phase equilibrium investigations of the adirondack class. Total alkali sodium plus potassium, expressed as oxides is a fair proxy for the alkali or atop modal dimension of the volcanic qap diagram, and silica total silicon as sio 2 is a fair proxy for the quartz or q direction. Underlying some 70 percent of the earths surface, basalts are the most abundant type of rock on the earth and the moon. However, with an understanding of the basics of crystallization and melting obtained through the study of phase diagrams for simple systems, it is possible to begin to. In that way, membrane proteins, reasonably grouped as a fourth component, could be examined in a systematic manner that is based on thermodynamic principles. Lecture notes phase diagram implications it is easy to get bogged down in the technical details of phase diagrams and loose sight of the goal of explaining igneous rocks. The mesostasis in lunar basalts does not alter as it would on the earth. Such projections often obscure relationships that would only be evident in a threedimensional tetrahedral plot. We have seen this done to a limited extent in our study of phase diagrams in igneous rocks and we will see more detail on this in the discussions that follow. Highpressure phase equilibria of a highmagnesia basalt and.
Igneous rocks of the ocean basins tulane university. Global systematics of ocean ridge basalts and their origin. Hence, mineralogic and textural relationships provide information on magma chemistry and conditions of crystallization. Lecture notes petrology earth, atmospheric, and planetary.
Construction of isomolar pseudoliquidus phase diagrams if pseudojiquidus phase diagrams are going to be valuable for testing and refining petrologic theory, it is obvious that some improvements must be made in exist. Tetrahedral plots of the phase relations f or basalts 879 at multiple saturation the phase assemblage is either eclogitic scpx,grt,l or scpx,spl,l cf. Solubility limit introduction solutions solid solutions, solute atoms dissolve in the solvent to form a solid solution a single phase mixtures more than one phase solubility limit. Tetrahedral plots of the phase relations for basalts. Textures and modal mineralogy can be related to cooling history and to the phase relationships detailed in simplified phase diagrams that relate to basaltic systems. These considerations then assist an evaluation of the relative stabilities of olivine and plagioclase in morb. Prentice hall commonly used normalization factors for spider diagrams are provided by sun and mcdonough. An introduction to igneous and metamorphic petrology. Pdf tetrahedral plots of the phase relations for basalts. The eutectic temperature and the eutectic composition 4. Hoover 2 1 department of geosciences, the university of texas at dallas, p.
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